学术论文
He W, Huang J, Sun X, Frontier AJ. Total Synthesis of (±)-Merrilactone A via Catalytic Nazarov Cyclization. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129: 498-499, 2007
发布时间：2011-11-16作者：何伟关键字：
| Abstract The total synthesis of merrilactone A (a neurotrophic agent) has been achieved. In the approach reported, simultaneous creation of the C-4 and C-5 stereocenters was accomplished stereospecifically using an unprecedented variant of the Nazarov cyclization. Additional studies focused upon this Lewis acid-catalyzed cyclization of a silyloxyfuran-containing intermediate are presented. |
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